منابع مشابه
ROMP from ROMP: A New Approach to Graft Copolymer Synthesis.
A new strategy is presented for the synthesis of graft copolymers using only the ring-opening metathesis polymerization (ROMP). From a ROMP-derived main chain, pendant maleimide functional groups are converted into norbornene moieties via a Diels-Alder reaction with cyclopentadiene. The norbornene groups serve as sites of initiation, and subsequent ROMP from the main chain yields graft copolyme...
متن کاملSynthesis and ROMP Chemistry of Decafluoroterphenoxide Molybdenum Imido Alkylidene and Ethylene Complexes
The bisDFTO alkylidene complexes of molybdenum Mo(NR)(CHCMe2Ph)(DFTO)2 (R = 2,6-i-Pr2C6H3, 2,6-Me2C6H3, C6F5, 1-adamantyl; DFTO = 2,6-(C6F5)2C6H3O) and monoaryloxide monopyrrolide (MAP) complexes Mo(NR)(CHCMe2Ph)(Me2Pyr)(OAr) (Me2Pyr = 2,5-dimethylpyrrolide; R = C6F5, OAr = DFTO, 2,6dimesitylphenoxide (HMTO); R = 2,6-Me2C6H3, OAr = DFTO) have been prepared in good yields. Addition of dicarbomet...
متن کاملAlgorithm: Regularized Orthogonal Matching Pursuit (ROMP)
This paper seeks to bridge the two major algorithmic approaches to sparse signal recovery from an incomplete set of linear measurements – L1-minimization methods and iterative methods (Matching Pursuits). We find a simple regularized version of the Orthogonal Matching Pursuit (ROMP) which has advantages of both approaches: the speed and transparency of OMP and the strong uniform guarantees of t...
متن کاملBranched Polymers via ROMP of Termimers.
Today's olefin metathesis catalysts show high reactivity, selectivity, and functional group tolerance and allow the design of new syntheses of precisely functionalized polymers. Here the synthesis of a new end-capping reagent is investigated allowing the introduction of a highly reactive activated ester end-group at the polymer chain end as well as its prefunctionalization to directly introduce...
متن کاملROMP Reactivity of endo- and exo-Dicyclopentadiene
The activation parameters for the ring-opening metathesis polymerization (ROMP) of endo(1) and exo-dicyclopentadiene (2), endo-1,2-dihydrodicylopentadiene (3), and norbornene (4) in the presence of Grubbs’ catalyst were determined using in situ NMR. The exo isomer of DCP was found to be more than an order of magnitude more reactive than the endo isomer. endo-DCP was found to have reactivity sim...
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ژورنال
عنوان ژورنال: Science
سال: 2005
ISSN: 0036-8075,1095-9203
DOI: 10.1126/science.309.5737.991b